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- Exploitation of agricultural waste as green starting materials to produce various valuable products is attracting the attention of academic, industrial and other practitioners. Cashew nut shell (CNS) and its liquid extract (CNSL) in particular have been identified as agro-wastes rich in valuable and functional renewable products. The unique structural features of the CNSL constituents offer the possibility for different modifications to suit various applications. This review article provides recent developments in CNS and CNSL as green sources for use in the production of biorenewable chemicals, materials and energy. Extraction methods and applications of CNS, CNSL and isolates are discussed. Furthermore, a literature survey of the current status and efforts made on the utilization of these agricultural and food wastes for different applications is well outlined.
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- A distorted single crystal structure of bis(piperidinedithiocarbamato)lead(II) complex and its subsequent use to deposit thin films is reported. Two deposition routes namely, aerosol-assisted chemical vapour deposition (AACVD) and spin coating deposition have been employed to obtain anisotropic lead sulfide (PbS) nanostructures. The thin films displayed rod to cubic shaped crystals for AACVD, and a range of cubes, star and dendritic morphologies with variation of temperatures were displayed for spin coated films. Optical band gaps between 1.32 and 1.55 eV as controlled by the change in temperature were observed for thin films deposited by AACVD. Powder X-ray diffraction (P-XRD) studies show that the films formed are composed of cubic crystalline PbS. The X-ray photoelectron spectroscopy (XPS) was used to investigate the effect of activation temperatures (350, 400 and 450 °C) on the chemical composition and oxidation states of PbS samples.
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