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- A series of Fe(III), Co(III), Ni(II), Cu(II), Zn(II) and In(III) N-morpholine-N'-benzoyl thiourea complexes have been synthesized and characterized by elemental analysis, thermal analysis, infrared spectroscopy, 1H nuclear magnetic resonance spectroscopy and single-crystal X-ray crystallography. Thermogravimetric analysis shows that all the complexes undergo a two-step decomposition process except for the iron(III) complex and the indium(III) complexes, which show three-step and one-step decompositions, respectively. The complexes are thermally stable up to approximately 300°C. The ligand coordinates the various metal ions in a bidentate (L-kO,S) chelating mode, facilitated by deprotonation of the acidic amide (–C(O) N'HC (S)) moiety. This mode of coordination allows for the facile formation of neutral bis/tris-6-membered chelates of type [M(L-kS,O)x] where x = 2 or 3 for divalent or trivalent metal ions, respectively.
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